by GarbageMan » Thu Jan 05, 2006 1:35 pm
My brain is like a golf ball driven in a tile bathroom with this.... I need to settle on one part. I'm trying to work it backwards:
If it's a balanced reaction and we end up with Nso4 and water then where did the N come from? In the coating, the catalyist, or in the solution. If the solution is (or becomes) H2So4 (remember this was for emergency use in vehicles so I'm figuring it's kind of a one shot deal and it might be better to "make" the sulfuric than to have a tank of it sloshing around), then what made the H2So4? Well, if the coating on the catalyist, then probably a solid or powder that's pressed/applied?
So... need a material that makes sulfuric and maybe has a Nitrogen in there somewhere. Only thing I found as of yet is Sulfamic acid:
NH2HSO3 + HNO2 ---> H2SO4 + H2O + N2
That HNO2 part might already be in solution. Then the sulfuric reacts with the metal catalyist and.........H2?
Just a tangent my brain took off on.......
Other thoughts.. what if the metals were already shorted? I mean, single cell/tank, then you drop in a compressed brillo/SOS pad except the soap was something else? Big S/A, small space, simple.
Also, Selenium conducts electricity better when light shines on it. Control mechanism?
One more... Phosphoric acid anion- check out the heat of formation and it sure likes to give up H's.
My brain hurts........