Conventional petrol has an octane rating which affects the amount of knock (detonation) you get when burning lesser amounts of that fuel.
If you switch a car to methanol, the calories per unit of fuel is much less, but you need to richen the mixture up to prevent detonation. Methanol requires about 2.5 times the amount of liquid fuel to run the same engine, however will be less likely to knock and because there is more fuel, will make more power.
Different fuels require different amounts to stave off the knock. And tuning any engine is where you are riding the fine line between knock and maximum power per bang. Sometimes this wastes fuel and sometimes you can burn up a lot. Methanol is a wasteful fuel, hence dragsters shoot spectacular flames out the exhaust, wheras, LPgas powered engines will burn the fuel much more efficiently.
It just so happens that with petrol, that around 14:1 oxygen:fuel ratio is the ideal amount to achieve efficient burning, power and minimal knock.
The old fashioned backyard way of tuning a car engine was to adjust things till it pinged (knocked) and back it off a smidge on the timing and add a bit more fuel. That was how it was done before o2 sensors and dynos were common.
I know this still doesn't answer the question but it does open up new questions like:
What is the octane rating of hydrogen?
Will it knock?
How can we measure the air:fuel ratio or is there another way?
If a conventional ICE requires 1% to 3% hydrogen to each unit of air drawn in, then if we're working with a conventional 2 litre engine, each cylinder will require 5 to 15ml of hydrogen per piston firing.
3000 revolutions is 6000 piston firings, so 6000 X 5ml is 30 litres of hydrogen gas per minute. Multiplied by the volumetric efficiency, so possibly knock off 1/3rd of this figure for most inefficient engines.
A turbo engine will guzzle double the amount for every 14psi of boost you run....
If hydrogen expands 1800 times it's size, you will need to convert approximately 17ml of water every minute to run the 2 litre engine in my example.
17ml of water replaces 100ml of petrol.
Now I know what all the fuss is about, these figures are sounding pretty good to me.